3) Simon Mignolet (8 Penalties Saved In 245 PL Apps)
The Belgian initially came to prominence during a spell with Sunderland before being snapped up by Liverpool in 2013. He spent six years at Anfield, although his performances were continually questioned.
Mignolet was, however, an expert at saving penalties and no Premier League forward relished the prospect of going up against him from 12 yards out. He is currently playing back in his native Belgium for Club Brugge.